Ah, now that is an interesting case. The answer to your question in this case is no, it does not account for daylight savings. If you set the time to 07:00 PDT then the datebase saves at as 00:00 UTC. Then outside daylight savings the cron will see that 00:00 UTC as 08:00 PST and I suspect that's also what it would show in the interface so you would have to manually adjust it to 07:00 PST (which would then be stored as 23:00 UTC)